352 research outputs found

    The integration of process planning and machine loading in small batch part manufacturing

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    PART is a highly automated planning system in which both process and production planning functions are integrated. This paper discusses a method to improve machine tool selection in process planning by integration with loading. A method is presented to select the best process plan from a number of possible alternatives taking into account the limited availability of resources. Various aspects of the quality of a process plan are evaluated and expressed in the so-called evaluation time. To prevent redundant work, partly worked out process plans are considered as alternatives. The consequences of the different alternatives have to be estimated which includes the estimation of machining times. The loading problem is modelled as the minimization of the total evaluation time for a given order set, subjected to capacity constraints

    Photodissociation Dynamics of the Iodine-Arene Charge-Transfer Complex

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    The photodissociation reaction of the molecular iodine:arene charge-transfer (CT) complex into an iodine atom and an iodine atom-arene fragment has been investigated using femtosecond pump-probe, resonance Raman, and molecular dynamics simulations. In the condensed phase the reaction proceeds on a time scale of less than 25 fs, in sharp contrast to the gas phase where the excited state lifetime of the complex is about 1 ps. Since little CT resonance enhancement is found in Raman studies on the I2-stretch vibration, it is concluded that rapid curve crossing occurs from the CT state to a dissociative surface. Of particular interest is the finding that the polarization anisotropy of the iodine atom:arene (I:ar) photoproduct decays on a time scale of 350 fs both in pure arene solvents as well as in mixed arene/cyclohexane solutions. This latter finding rules out that secondary I:ar complex formation is the main cause of this ultrafast depolarization effect. The initial polarization anisotropy is found to be ~0.12 in pure mesitylene and ~0.34 in mixed mesitylene/cyclohexane solutions. Semiempirical configuration-interaction calculations show that, except for the axial CT complex, the transition dipole is aligned almost parallel to the normal of the arene plane. The oscillator strength of the CT transition is found to be maximal in the oblique conformation with the I2 molecule positioned at an angle of about 30° with respect to the arene normal. This iodine angular dependence of the oscillator strength leads to photoselection of bent I2:ar complexes in pump-probe experiments. Molecular dynamics simulations confirm earlier findings that the I2:benzene complex is a fragile entity and that it persists only for a few hundred femtoseconds. These simulations also provide the proper time scale for the decay of the polarization anisotropy. The fact that the photoproduct experiences a substantial torque in the dissociation process explains the absence of a cage effect in this reaction.

    Estimates of future discharges of the river Rhine using two scenario methodologies: direct versus delta approach

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    International audienceSimulations with a hydrological model for the river Rhine for the present (1960?1989) and a projected future (2070?2099) climate are discussed. The hydrological model (RhineFlow) is driven by meteorological data from a 90-years (ensemble of three 30-years) simulation with the HadRM3H regional climate model for both present-day and future climate (A2 emission scenario). Simulation of present-day discharges is realistic provided that (1) the HadRM3H temperature and precipitation are corrected for biases, and (2) the potential evapotranspiration is derived from temperature only. Different methods are used to simulate discharges for the future climate: one is based on the direct model output of the future climate run (direct approach), while the other is based on perturbation of the present-day HadRM3H time series (delta approach). Both methods predict a similar response in the mean annual discharge, an increase of 30% in winter and a decrease of 40% in summer. However, predictions of extreme flows differ significantly, with increases of 10% in flows with a return period of 100 years in the direct approach and approximately 30% in the delta approach. A bootstrap method is used to estimate the uncertainties related to the sample size (number of years simulated) in predicting changes in extreme flows

    The diurnal cycle of shallow cumulus clouds over land: A single-column model intercomparison study

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    An intercomparison study for single-column models (SCMs) of the diurnal cycle of shallow cumulus convection is reported. The case, based on measurements at the Atmospheric Radiation Measurement program Southern Great Plains site on 21 June 1997, has been used in a large-eddy simulation intercomparison study before. Results of the SCMs reveal the following general deficiencies: too large values of cloud cover and Cloud liquid water, unrealistic thermodynamic profiles, and high amounts of numerical noise. Results are also strongly dependent on vertical resolution.These results are analysed in terms of the behaviour of the different parametrization schemes involved: the convection scheme, the turbulence scheme, and the cloud scheme. In general the behaviour of the SCMs can be grouped in two different classes: one class with too strong mixing by the turbulence scheme, the other class with too strong activity by the convection scheme. The coupling between (subcloud) turbulence and the convection scheme plays a crucial role. Finally, (in part) motivated by these results several models have been successfully updated with new parametrization schemes and/or their present schemes have been successfully modifie

    Soil control on runoff response to climate change in regional climate model simulations

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    Simulations with seven regional climate models driven by a common control climate simulation of a GCM carried out for Europe in the context of the (European Union) EU-funded Prediction of Regional scenarios and Uncertainties for Defining European Climate change risks and Effects (PRUDENCE) project were analyzed with respect to land surface hydrology in the Rhine basin. In particular, the annual cycle of the terrestrial water storage was compared to analyses based on the 40-yr ECMWF Re-Analysis (ERA-40) atmospheric convergence and observed Rhine discharge data. In addition, an analysis was made of the partitioning of convergence anomalies over anomalies in runoff and storage. This analysis revealed that most models underestimate the size of the water storage and consequently overestimated the response of runoff to anomalies in net convergence. The partitioning of these anomalies over runoff and storage was indicative for the response of the simulated runoff to a projected climate change consistent with the greenhouse gas A2 Synthesis Report on Emission Scenarios (SRES). In particular, the annual cycle of runoff is affected largely by the terrestrial storage reservoir. Larger storage capacity leads to smaller changes in both wintertime and summertime monthly mean runoff. The sustained summertime evaporation resulting from larger storage reservoirs may have a noticeable impact on the summertime surface temperature projections

    Tales of future weather

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    Society is vulnerable to extreme weather events and, by extension, to human impacts on future events. As climate changes weather patterns will change. The search is on for more effective methodologies to aid decision-makers both in mitigation to avoid climate change and in adaptation to changes. The traditional approach uses ensembles of climate model simulations, statistical bias correction, downscaling to the spatial and temporal scales relevant to decision-makers, and then translation into quantities of interest. The veracity of this approach cannot be tested, and it faces in-principle challenges. Alternatively, numerical weather prediction models in a hypothetical climate setting can provide tailored narratives for high-resolution simulations of high-impact weather in a future climate. This 'tales of future weather' approach will aid in the interpretation of lower-resolution simulations. Arguably, it potentially provides complementary, more realistic and more physically consistent pictures of what future weather might look like

    Temporal Evolution of Serum Concentrations of High-Sensitivity Cardiac Troponin During 1 Year After Acute Coronary Syndrome Admission

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    Background Detailed insights in temporal evolution of high-sensitivity cardiac troponin following acute coronary syndrome (ACS) are currently missing. We aimed to describe and compare the post-ACS kinetics of high-sensitivity cardiac troponin I (hs-cTnI) and high-sensitivity cardiac troponin T (hs-cTnT), and to determine their intra- and interindividual variation in clinically stable patients. Methods and Results We determined hs-cTnI (Abbott) and hs-cTnT (Roche) in 1507 repeated blood samples, derived from 191 patients with ACS (median, 8/patient) who remained free from adverse cardiac events during 1-year follow-up. Post-ACS kinetics were studied by linear mixed-effect models. Using the samples collected in the 6- to 12-month post-ACS time frame, patients were then considered to have chronic coronary syndrome. We determined (differences between) the average hs-cTnI and average hs-cTnT concentration, and the intra- and interindividual variation for both biomarkers. Compared with hs-cTnT, hs-cTnI peaked higher (median 3506 ng/L versus 494 ng/L; P<0.001) and was quicker below the biomarker-specific upper reference limit (16 versus 19 days; P<0.001). In the post-6-month samples, hs-cTnI and hs-cTnT showed modest correlation (rspearman
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